| Achievement/Trophy | Description |
| DOA5 Last Round Master | Unlock all achievements. |
| Fighting Entertainment | Have your first fight outside of Training or Versus modes. |
| Rivals | Register a fighter in your Fighter List. |
| Rival Rumble | Fight online. |
| Rival Rampage | Fight online 10 times. |
| DOA5 Last Round Is My Life | Fight online 100 times. |
| My Fight, My Rules | Create your own online lobby. |
| Get Out There and Fight! | Play a Lobby match. |
| Fighting for Real | Play a Ranked match. |
| Gesundheit! | Trigger the Special Danger Zone in The Show. |
| Tango Kilo November | Trigger the Special Danger Zone in Hot Zone. |
| Catch and Release | Trigger the Special Danger Zone in Sky City Tokyo. |
| You Asked for It! | Set "Throwdowns" to "Accept" and have a Throwdown in Versus, Arcade, or Free Training mode. |
| Anybody, Anytime, Anywhere | Set "Throwdowns" to "Accept" and have 10 Throwdowns in Versus, Arcade, or Free Training mode. |
| Arcade (Solo) Cleared | Clear 1 course in Arcade (solo) mode. |
| Arcade (Tag) Cleared | Clear 1 course in Arcade (tag) mode. |
| Time Attack (Solo) Cleared | Clear 1 course in Time Attack (solo) mode. |
| Time Attack (Tag) Cleared | Clear 1 course in Time Attack (tag) mode. |
| Survival (Solo) Cleared | Clear 1 course in Survival (solo) mode. |
| Survival (Tag) Cleared | Clear 1 course in Survival (tag) mode. |
| Fledgling Fighter | Fight a Versus (solo) match. |
| You're It | Fight a Versus (tag) match. |
| Training Hard | Play Free Training mode for 1 hour. |
| Exercise Newbie | Complete all moves for a character in Command Training. |
| Your Education Begins Now | Play in Tutorial. |
| A Fighter is Born | Complete all lessons in Tutorial. |
| A New Challenger Appears! | Played in Combo Challenge. |
| Unchallenged Champion | Complete all lessons for a character in Combo Challenge. |
| On the Edge of Your Seat | Play Spectator mode. |
| Fighter, Know Thyself | View your results in Fight Record. |
| Ahhh, Memories | View your photos in the Album. |
| Say Cheese! | Take a photo in Spectator mode. |
| How Do I Fight? | Display the Move List. |
| How Do I Fight Like a Pro? | Display the Move Details. |
| A Fight to Remember | Save a replay. |
| Turn It Up | Change the background music settings. |
| Who's Got Popcorn | Watch a movie. |
| Safety First | Turn Danger Zones off on the Stage Select screen. |
| Power in Numbers | Have a Team Fight. |
| First Tag Team | Fight a tag match. |
| The Power of Two | Do 10 different character-specific tag throws. |
| Blow Em Away | Successfully land a Power Blow. |
| We Have Liftoff! | Successfully deliver a Power Launcher. |
| Change of Power | Press H+P+K during a Power Blow to tag in a partner and deliver a Tag Power Blow. |
| Down You Go | Successfully attack during a Cliffhanger. |
| Cliffhanger Comeback | Successfully block an opponent's attack during a Cliffhanger. |
| I Read Every Move | Win without taking any damage. |
| Failure Teaches Success | See 8 characters' losing poses. |
